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Look at the subkeys of the following registry key and check the path for the Administrator.
HKEY_LOCAL_MACHINE\SOFTWARE\Microsoft\Windows NT\CurrentVersion\ProfileList
Or, and this is actually the most accurate way, reboot to safe mode and logon to the Administrator account. Now create a text file on the desktop named test. Go back to your user account in normal mode and see which of the Administrator Desktop folders has the test document. I'd bet on Administrator.Private001
The Windows system files are in the C:\Windows folder, though I'd guess you have 3 of those now too. Likely the C:\Windows.Private001 folder is the current one. Click Start>Run and type %systemroot% then hit enter and see where it takes you. Alternatively, open a command window then type set and hit Enter. Check the path in the Systemroot entry.
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